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Influences of Corrosion on the Coating Structure and Properties

Time:2021-01-06 21:10:00  From:  Author:

 

The cross-sectional microstructure of the as-sprayed and corroded coatings are shown in Fig.1.The phase contents were determined using phase analysis software.In the as-sprayed coatingthe ratio of metal to nonmetallic phase was 63 to 37.In the corroded coatingthis ratio was 40 to60.Figure 1 clearly shows that the increase in nonmetallic phasecomposed of pores filled by resin and boron nitride phaseresulted from the pore increase.Alsothere are some corrosion products found in the section imageFig.1b.

 

Fig.1 SEM images of the as-sprayed coating section (a) and corroded coating section (b)

Surface Brinell hardness tests were conducted on the as-sprayed and corroded coatings.The average indentation diameter of the as-sprayed coating was 2.61 mm.After undergoing a 96-h salt spray testthe average indentation diameter was 2.68 mm.The corresponding Brinell hard-ness was 10.8 HBSD 0.05and 10.2 HBSD 0.21),indicating that the hardness of the corroded coating decreased by approximately 6%in comparison with the as-sprayed coating.

The tensile bonding strengths of the as-sprayed coatings and coatings that underwent different salt-spray corrosion durations were tested according to the Chinese industry standardHB20035-2013.Resin glueFM-1000was used to bind the coating surface to the holder.A tensile testing machineAG-250KNEINSTRONUSAwas used to test the bonding strengthand the extension rate was 1 mm/min.The average bonding strength of the as-sprayed coating was 9.2±1.46 MPa.After testing in salt spray for 48hthe average bonding strength of the coating decreased to4.4±1.08MPafor 96 hand the average bonding strength decreased to 2.69 MPa.Observations of the tested coating samplesFig.2ashowed that the fracture occurred only in the surface layer of the coating that underwent 48h of salt sprayso only the binding layer was exposed.Whenthe coating experienced 96 h of salt sprayFig.2b),frac-tures at the interface between the substrate and bonding layer were observedso the corroded substrate was exposed.Corrosion had important effects on the coating bonding strength.

 

Fig.2 Fracture appearances of the tensile bonding strength test of the coating corroded for 48 h(a) and 96 h(b)


 

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